Product ID:PN:LP777 LIQUIFIED PETROLEUM GAS(LPG)-PROPANE
MSDS Date:07/01/1996
FSC:4940
NIIN:01-144-6766
MSDS Number: CHQMB

TURNER CO DIV OF CLEANWELD PRODUCTS CO

821 PARK AVE
SYCAMORE, IL 60178-2419
US

Emergency Phone: 815-895-4545

Info Phone: 815-895-4545

Cage: 61112

TURNER CO DIV OF CLEANWELD PRODUCTS CO

6200 SYCAMORE, IL 60178-2419 US

Telephone: 815-895-4545

Cage: 61112

PROPANE

CAS: 74-98-6

RTECS: TX2275000

Fraction By Weight: >90%

OSHA PEL 1000 PPM

ACGIH TLV: ASPHYXIANT; 9596

PROPYLENE (PROPENE) (SARA 313)

CAS: 115-07-1

RTECS: UC6740000

Fraction By Weight: <5%

ACGIH TLV: ASPHYXIANT; 9596

BUTANE

CAS: 106-97-8

RTECS: EJ4200000

Fraction By Weight: <2.5%

OSHA PEL 800 PPM

ACGIH TLV: 800 PPM; 9596

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE/SKIN:CONTACT W/LIQ MAY CAUSE
FROSTBITE.INHAL:HUMANS EXPO TO 10000PPM NBUTANE FOR 10MINS EXHIBITE
DROWS BUT NO OTHER EVIDENCE OF SYSTEMIC EFFECTS.ACCUMULATION OF HI
CONCEN MAY CAUSE CNS DEPRESS OR DISPLACE ATM OXY CAUSING
SUFFOCATION.INGST:NOT ANTICIPATED AS PROD IS GAS.
Explanation of Carcinogenicity:PER
MSDS:CARCINOGENICITY:NTP/OSHA/IARC:NO.
Effects of Overexposure:INGEST:GAS.SKIN;PROPANE W/ISOBUTANE IN
DEODERANT/ANTIPERSPIRANT PROD(65-71% WT)WAS NOT SHOWN TO CAUSE SKIN
IRRIT IN HUMAN VOLUNT(AERO APPLIED 2X DAILY,12WKS).EYE:NO
DATA.INHAL:NO SUBJ PHYS RESPONSES,E XPO RELATED CARDIAC ABNORM/PULM
FUNCTION ABNOR REPORTED IN VOLUNT EXPO TO
PROPANE.NUMB,HEAD,VOMIT,CHILL FEEL GAS ESCAPED
Medical Cond Aggravated by Exposure:NONE KNOWN. TARGET
ORGANS:RESPIRATORY SYSTEM, CNS.

First Aid:EYE:GAS-FLUSH W/LUKEWARM H2O FOR 15MINS.IRIT DVLPS SEEK MED
ATTN.LIQ-OPEN EYES WIDE TO ALLOW LIQ TO EVAPORATE.SEEK IMMED MED
ATN.SKIN:GAS-FLUSH W/LUKEWARM H2O FOR 15MINS.IRRIT PERSISTS SEEK
MED ATTN.L IQ-FROSTBITE OCURS SEEK MED ATTN.INHAL:REMOVE TO FRESH
AIR.BREATH DIFF ADMIN OXY;BREATH STOP GIVE ART RESP.SEEK MED
ATTN.OTHER:NOT ANTICIPATED.IF CRYOGENIC LIQ ACCIDENTALLY INGEST
SEEK IMMED MED ATTN.

Flash Point Method:CC
Flash Point:-155F,-104C
Autoignition Temp:Autoignition Temp Text:NP
Lower Limits:2 PROPANE
Upper Limits:9.5 PROPANE
Extinguishing Media:SM-DRY CHEM,FOAM,CO2.LG-H2O SPARY/FOG.STOP GAS FLOW
BEF ATTEMPT EXTI.CONT GAS FLOW CREATE EXPLO GAS/AIR MIX-IGN MORE
HAZ
Fire Fighting Procedures:FIREFIGHTERS SHOULD WEAR NIOSH/MSAH-APPROV
SELF-CONTAINED BREATHING APPARATUS OPERATED IN POSITIVE PRESSURE
MODE & FULL TURNOUT GEAR OR BUNKER GEAR.
Unusual Fire/Explosion Hazard:THERM DECOMPO PROD CARBON OXIDES.HIGHLY
FLAMM/EXPLO.VAP TRAVEL TO IGN SOURCE,FLASHBACK.VAP HEAVIER THAN
AIR,MAY TEND TO ACCUMULATE IN LOWLYING AREAS.EXPLO(SUPP)

Spill Release Procedures:EXT/REMOVE ALL IGN SOURCES.REMOVE CNTNR TO
OUTSIDE IF POSSIBLE;NOT POSSIBLE ISOLATE HAZ AREA-DENY ENTRY TO
UNAUTHORIZED/UNPROT PERSONNEL.VAP TRAVEL CONSIDERABLE DISTANCE TO
IGN SOURC-FLASHBACK.VENTI E NCLSD AREAS.FOUSH LG SPILLS
W/H2O.CLEANUP H2O(SUP)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:BOND/GROUND ALL LINES/EQPMT ASOSC
W/PROD SYS.ELECT EQPMT SHOULD BE NONSPARK/EXPLO PROOF.USE ONLY
W/ADEQU VENTI.EMPTY CNTNR MAY CONTAIN FLAMM RESIDUE.
Other Precautions:DISPO/HNDL EMPTY CNTNR ACCORDINGLY.PROT FRM PHYS
DMG.DONT DRAG/SLIDE/ROLL CYL.USE SUITABLE HAND TRUCK.STORE URIGHT
IN COOL DRY WELL VENTI AREA AWAY FRM EMERG EXIST,OTHER FLAMM,HEAVY
TRAVEL AREA.CYL TE MPS SHOULDNY EXCEED 120F.1ST IN 1ST OUT.

Respiratory Protection:UNDER NORMAL CONDITOINS (AMBIENT TEMPERATURE AND
PRESSURE) AND USE NONE REQUIRED.
Ventilation:LOC EXHA VENTI AS NECESSARY-PREVENT CONC FRM EXCEED EXPO
GUIDELINES/PREVENT EXPLO CONC BUILDUP.ELECT EPQMT SUIT FLAM ATM
Protective Gloves:NROPRENE,PLASTIC,RUBBER GLOVES
Eye Protection:SAF GOGG/GLASSES,FCSHIELD FOR CRYOGEN LQ
Other Protective Equipment:EMERG SHOWER/EYEWASH STATIONS.AIR SMPL FOR
BUTANE-COCNUT CHARCOAL SOBENT TUBE,FOR PROPANE-ANASORB CMS.
Work Hygienic Practices:DONT SMOKE IN WORK/STORAGE AREA;SIGNS SHOULD BE
POSED.CHANGE CONTAM CLOTH IMMED-FIRE/EXPLO HAZ.WASH HANDS AFT
HNDLG.
Supplemental Safety and Health
FIRE/EXPLO:HAZ INDOORS,OUTDOORS,CONF AREAS.CYL MAY EXPLO IF EXPO TO
HEAT/FLAME.FIRE PRESENT IN STORAGE AREA,DONT ENTER.CONT TO COOL
FLAME EXPO CNTNR W/H2O TIL WELL AFT FLAMES HAVE BEEN EXTINGUISHED.
S PILL:RUNOFF TO SEWERS MAY CAUSE FIRE/EXPLO.DONT REENTER TIL PROD
SUFFIC DISPERSED.CLEANUP PERSON WEAR APPRO PPE,RESP PRO

HCC:G2
Boiling Pt:B.P. Text:-44F,-42C
Melt/Freeze Pt:M.P/F.P Text:305F,152C
Decomp Temp:Decomp Text:NP
Vapor Pres:300PSIG
Vapor Density:1.52
Spec Gravity:0.51 LIQ
pH:NA
Viscosity:GAS
Evaporation Rate & Reference:NP
Solubility in Water:NEGLIGIBLE
Appearance and Odor:COLORLESS GAS, PUNGENT(MERCAPTAN ADDITIVE)ODOR
Percent Volatiles by Volume:GAS
Corrosion Rate:NP

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS.PROPANE AND CHLORINE DIOXIDE CAN EXPLODE ON CONTACT.
Stability Condition to Avoid:DONT HEAT CYL BY ANY MEANS.DONT CARRY IN
ENCLSD SPACE(CAR TRUCK,VAN,STATION WAGON)-ACCIDENTAL
RELEASE-ASPHYX,FIRE,EXPLO.
Hazardous Decomposition Products:THERMAL DECOMPOSITION WILL PRODUCE
CARBON OXIDES.

Waste Disposal Methods:VOLAT TO ATM EXPECT TO BE DOMINANT FATE
PROCESS.IN ATM RX W/PHOTOCHEM PROD HYDROXYL RADICALS W/AVG ATM
1/2LIVES 6/12 DAYS RESP.DISPO OF IAW APPLIC LOC/STATE/FED
REGS.DISPO PER 40CFR261,262.CAA TQ=1000 0LBS.SARA 313 CHEMS.

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